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In a saucepan, whisk together the vinegar and cornstarch until fully dissolved and no white bits of cornstarch remain. Add honey, Simon's Secret Sauce, onion powder, cayenne, and brown sugar. Whisk to combine, simmer over medium heat and continue whisking until glaze is reduced a bit, 5 minutes. Divide and reserve half of the glaze for serving. Keep other half of glaze for basting.
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Pat chops dry with paper towels. In a small bowl, combine 1/2 tsp kosher salt with 1/2 tsp freshly ground black pepper. Sprinkle chops evenly with salt/pepper combination.
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Grease grill and preheat on medium-high. Grill chops about 3-4 min per side, or just until center is cooked. Don't over cook. Brush chops with glaze that was reserved for basting and grill another minute per side.
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Serve with reserved glaze drizzled over cooked chops.